- 백금산화촉매를 통한 이산화질소(NO2)의 저감 특성에 관한 실험적 연구
- ㆍ 저자명
- 김영득,조자윤,이정길,김우승,Kim. Young-Deuk,Cho. Ja-Yun,Lee. Jung-Gil,Kim. Woo-Seung
- ㆍ 간행물명
- 한국자동차공학회논문집
- ㆍ 권/호정보
- 2012년|20권 4호|pp.142-149 (8 pages)
- ㆍ 발행정보
- 한국자동차공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The reduction characteristics of $NO_2$ to NO are experimentally studied over a platinum-based catalyst, especially at lower temperatures below about $200^{circ}C$. In the present work, two types of steady-state experiments, engine bench and synthetic gas bench tests, are carried out in sequence. Steady-state engine bench tests with the DOC mounted on a light duty 4-cylinder 2.0 liter turbocharged diesel engine are performed and prove that CO plays a major role in $NO_2$ abatement at temperatures below the light-off temperature of CO oxidation, about $200^{circ}C$. Synthetic gas bench tests are then performed using synthetic gas mixtures with CO, $C_3H_6$, NO, $NO_2$, $O_2$, $H_2O$ and $N_2$ in the $140{sim}450^{circ}C$ T-range and show that both CO and $C_3H_6$ are capable of reducing $NO_2$. It is noted that the reaction rate of $NO_2$ with $C_3H_6$ is much higher than that with CO. At temperatures below about $200^{circ}C$, the reduction of $NO_2$ to NO is promoted with increasing CO concentration and $NO_2$/$NO_X$ ratio and with decreasing $O_2$ concentration, as well as with the presence of $H_2O$.