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Effect of Al Content on the Gas-Phase Dehydration of Glycerol over Silica-Alumina-Supported Silicotungstic Acid Catalysts
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  • Effect of Al Content on the Gas-Phase Dehydration of Glycerol over Silica-Alumina-Supported Silicotungstic Acid Catalysts
  • Effect of Al Content on the Gas-Phase Dehydration of Glycerol over Silica-Alumina-Supported Silicotungstic Acid Catalysts
저자명
Kim. Yong-Tae,You. Su-Jin,Jung. Kwang-Deog,Park. Eun-Duck
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2012년|33권 7호|pp.2369-2377 (9 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The gas-phase dehydration of glycerol to acrolein was carried out over silicotungstic acid ($H_4SiW_{12}O_{40}{cdot}xH_2O$, HSiW) catalysts supported on $SiO_2$, ${eta}-Al_2O_3$, and silica-aluminas with different Al contents. The HSiW catalysts supported on silica-aluminas showed higher glycerol conversions and acrolein yields during the initial 2 h at $315^{circ}C$ than did $SiO_2$- and ${eta}-Al_2O_3$-supported HSiW catalysts. Among the tested catalysts, HSiW/$Si_{0.9}Al_{0.1}O_x$ exhibited the highest space-time yield during the initial 2 h. The loaded HSiW species can change the acid types and suppress the formation of carbonaceous species on Al-rich silica-aluminas. The deactivated HSiW supported on silica-aluminas can be fully regenerated after calcination in air at $500^{circ}C$. As long as the molar ratio between water and glycerol was in the range of 2-11, the acrolein selectivity increased significantly with increasing water content in the feed, while the surface carbon content decreased owing to the suppression of heavy compounds.