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STUDY OF n-$C_{12}H_{26}$ REFORMING OVER DFC CATALYST IN A SIMULATED DIESEL EXHAUST
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  • STUDY OF n-$C_{12}H_{26}$ REFORMING OVER DFC CATALYST IN A SIMULATED DIESEL EXHAUST
  • STUDY OF n-$C_{12}H_{26}$ REFORMING OVER DFC CATALYST IN A SIMULATED DIESEL EXHAUST
저자명
Lee. J.,Song. S.,Chun. K.M.
간행물명
International journal of automotive technology
권/호정보
2012년|13권 1호|pp.23-31 (9 pages)
발행정보
한국자동차공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

In lean-DeNOX catalysis reactions, hydrogen is a good reducing agent in PGM catalysts as well as an effective promoter in selective catalytic reduction reactions over base metal oxide catalysts. However, such a lean-DeNOX system, which uses hydrogen, requires an on-board fuel reforming system applicable to internal combustion engines. In this study, catalytic partial oxidation (CPOx) performance was tested in a laboratory for various reactants and hydrocarbon conditions. Volume concentrations of 5-10% oxygen and 0-5% water vapor were used to simulate diesel exhaust, and n-$C_{12}H_{26}$ was used as the feedstock for the reforming reaction. In the CPOx of n-$C_{12}H_{26}$, the highest hydrogen selectivity was 64% and was achieved at 100,000 h-1 GHSV. Additionally, the C/O ratio was less than unity in the absence of water vapor. However, as the water concentration was increased to 2.5 and 5.0 vol. % in the n-$C_{12}H_{26}$ CPOx reactions, the maximum hydrogen selectivity was increased from 64% in the absence of water to 70% and 75%, respectively. This effect is a consequence of the water-gas shift reaction over the catalyst bed. Regarding oxygen concentration effects, hydrogen selectivity slightly increased with increasing oxygen concentration from 10% to 15%. It was also found that the CPOx reaction of n-$C_{12}H_{26}$ can be ignited at temperatures below 300 C. Accordingly, it can be concluded that CPOx is a useful and feasible device for promoting diesel DeNOx catalysis in terms of hydrogen productivity and reaction initiation.