This paper suggests the online method to identify normal and abnormal state of water quality on the ocean USN. To define normal of the ocean water quality, we utilize the negative selection algorithm of artificial immunity system which has self and nonself identification characteristics. To distinguish abnormal status, normal state set of the ocean water quality needs to be defined. For this purpose, we generate normal state set base on mutations of each data and mutation of the data as logical product. This mutated normal (or self) sets used to identify abnormal status of the water quality. We represent the experimental result about mutated self set with the Gaussian function. Through setting the method on the ocean sensor logger, we can monitor whether the ocean water quality is normal or abnormal state by online.