An unsteadily propagating permeable crack in piezoelectric materials (PMs) under anti-plane shear mechanical loading and in-plane electric loading is studied. The equilibrium equations for a transiently propagating crack in a PM are developed, and the solutions on the stress and displacement fields for a permeable crack though an asymptotic analysis are obtained. The influences of piezoelectric constant, dielectric permittivity, time rate of change of the crack tip speed and time rate of change of stress intensity factor on the stress and displacement fields at the transiently propagating crack tip are explicitly clarified. By using the stress and displacements, the characteristics of the stress and displacement at a transiently propagating crack tip in a PM are discussed.