기준재령 염소이온 확산계수를 측정하기 위하여 고성능 콘크리트 배합을 선정하고 공시체를 제작하였다. 배합은 해양환경에 건설되는 교량에 적합하도록 선정되었으며 배합설계 변수는 결합재 종류, 물-결합재비, 광물질 혼화재 치환율, 잔골재 종류, 고강도 및 고유동성을 얻기 위한 화학 혼화제 종류, 목표 슬럼프 또는 슬럼프 플로우이다. 시험 결과로부터 기준재령 염소이온 확산계수는 결합재 종류와 그 치환율에 따라 크게 다름을 확인하고, 결합재 종류와 치환율을 고려한 기준재령 확산계수 모델을 개발하였다. 개발된 모델의 확산계수를 기존 모델의 확산계수 및 추가 확산 계수 측정시험 결과 비교하여 개발된 모델의 타당성을 확인하였다.
High performance concrete mixes are selected and corresponding test specimens are made for the study of chloride diffusion coefficient at reference time. The concrete mixes were same designs as those used in construction of bridges located in a marine environment. Mix design variables included binder type, water-to-binder ratio, mineral admixtures to total binder weight substitution ratio, fine aggregate source, chemical water reducer admixture type for high strength and high flowability, and target slump or slump flow. The test results showed that the diffusion coefficients at reference time varied significantly according to the type of mineral admixtures and their substitution ratios. A model for diffusion coefficient at reference time considering the type of mineral admixture and the substitution ratio was developed. Diffusion coefficients from the developed model were compared with those from literature review, a previous model, and additional test results. All of the comparisons verified that the developed model can reasonably predict diffusion coefficients and the application of the model to the durability design against chloride penetration is appropriate.
