In an earlier work, we proposed the chromatic dispersion monitoring technique of non-return to zero (NRZ) signal based on clock-frequency component (CFC) through numerical simulations. However, we have not yet shown any experimental demonstration or analytic derivation of it. In this paper, we show an experimental demonstration and analytic derivation of the proposed chromatic dispersion monitoring technique. We confirm that the experimental results and the analytic results correspond with the simulation results. We also demonstrate that monitoring range and accuracy can be improved by using a simple clock-extraction method.