In this paper, a new development in the time optimal control theory in sliding mode control systems for multi-quadrant buck converters with a variable load is presented. In general, the closed-loop time optimal control system is applied to multi-quadrant buck converters for output regulation, so that an optimal switching surface is obtained. Moreover, an adjusted optimal sliding mode controller is suggested which adjusts the controller parameters to give an optimal switching surface. In addition, a description of the transient response of the closed-loop system is proposed and used to damp any output or input disturbances in minimum time. Numerical simulations and experimental results are employed to demonstrate that the output regulation time and transient performances of dc/dc converters using the proposed technique are improved effectively when compared to the classical sliding mode control method.