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가압 유동층 반응기에서 SEWGS 공정을 위한 WGS 촉매의 반응특성
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  • 가압 유동층 반응기에서 SEWGS 공정을 위한 WGS 촉매의 반응특성
저자명
김하나,이동호,이승용,황택성,류호정,Kim. Ha-Na,Lee. Dong-Ho,Lee. Seung-Yong,Hwang. Taek-Sung,Ryu. Ho-Jung
간행물명
한국수소 및 신에너지학회 논문집
권/호정보
2012년|23권 4호|pp.337-345 (9 pages)
발행정보
한국수소및신에너지학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

To check effects of operating variables on reaction characteristics of WGS catalyst for SEWGS process, water gas shift reaction tests were carried out in a pressurized fluidized bed reactor using ShiftMax210 catalyst and sand(as a substitute for $CO_2$ absorbent) as bed materials. Simulated syngas(mixed with $N_2$) was used as a reactant gas. Operating temperature was $210^{circ}C$ and operating pressure was 20 bar. WGS catalyst content, steam/CO ratio, gas velocity, and syngas concentration were considered as experimental variables. CO conversion increased as the catalyst content and steam/CO ratio increased. CO conversion at fluidized bed condition was higher than that of fixed bed condition. However, CO conversion were maintained almost same value within the fluidized bed condition. CO conversion decreased as the syngas concentration increased. The optimum operation condition was confirmed and long time water gas shift reaction test up to 24 hours at the optimum operating conditions was carried out.