In Korea more than 38,000 types of hazardous material(HAZMAT) are distributed, accordingly the accidents during transportation are also increasing. The agencies related to HAZMAT such as Environment Ministry, National Emergency Management Agency and National Police Agency have their own regulations. However, the classification criteria of HAZMAT are different to each other, which causes many problems in response to transportation accidents. In this study the classification standard of HAZMAT and the classification code using CAS number are suggested to manage HAZMAT efficiently. Through efficient management and standard classification of HAZMAT, the rapid and systematic response to transportation accidents related to HAZMAT is expected to be possible.