- 마그네슘 열환원에 의한 저응집 초미립 TiCN 분말합성
- ㆍ 저자명
- 이동원,Lee. Dong-Won
- ㆍ 간행물명
- 한국분말야금학회지
- ㆍ 권/호정보
- 2012년|19권 5호|pp.356-361 (6 pages)
- ㆍ 발행정보
- 한국분말야금학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The ultra-fine and less agglomerated titanium carbonitride particles were successfully synthesized by magnesiothermic reduction with low feeding rate of $TiCl_4+1/4C_2Cl_4$ solution. The sub-stoichiometric titanium carbide ($TiC_{0.5{sim}0.6}$) particles were produced by reduction of chlorine component by liquid magnesium at $800^{circ}C$ of gaseous $TiCl_4+1/4C_2Cl_4$ and the heat treatments in vacuum were performed for 5 hours to remove the residual magnesium and magnesium chloride mixed with produced $TiC_{{sim}0.5}$. The final $TiC_{{sim}0.5}N_{0{sim}0.5}$ particle with near 100 nm in mean size and high specific surface area of $65m^2/g$ was obtained by nitrification under nitrogen gas at $1,150^{circ}C$ for 2 hrs.