In this paper, an experimental and numerical investigation of transition characteristics in a square-sectional curved duct flow under Centrifugal force is presented. The experimental study is carried out to measure axial velocity profiles by using Laser Doppler Velocimeter (LDV) system. Computational fluid dynamic (CFD) simulation was performed using the commercial CFD code FLUENT to investigate the transition characteristics. The flow development is found to depend upon Dean number and curvature ratio. The velocity profiles in center of the duct have lower value than those of the inner and outer walls because of the centrifugal forces.