A Novel 3D Polypseudo-rotaxane Metal-organic Framework Based on a Flexible Bis-pyridyl-bis-amide Ligand

A Novel 3D Polypseudo-rotaxane Metal-organic Framework Based on a Flexible Bis-pyridyl-bis-amide Ligand
A Novel 3D Polypseudo-rotaxane Metal-organic Framework Based on a Flexible Bis-pyridyl-bis-amide Ligand

ㆍ 저자명: Wang. Xiu-Li,Han. Na,Lin. Hong-Yan,Xu. Chuang,Luan. Jian,Liu. Guo-Cheng
ㆍ 간행물명: Bulletin of the Korean Chemical Society
ㆍ 권/호정보: 2012년|33권 11호|pp.3793-3796 (4 pages)
ㆍ 발행정보: 대한화학회
ㆍ 파일정보: 정기간행물|ENG|
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ㆍ 주제분야: 기타

이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.

서지반출

기타언어초록

A novel 3D compound ${[Cu(L)(H_2O)_4][Cu_2(SIP)_2(L)_2]}{cdot}2H_2O$ (1) (L = N,N-bis(4-pyridinecarboxamide)-1,4-butane, SIP = 5-sulfoisophthalate) is hydrothermally synthesized. X-ray diffraction analysis reveals that compound 1 is composed of 2D anionic $[Cu_2(SIP)_2(L)_2]_n{^{2n-}}$ double-layers and discrete 1D cationic $[CuL(H_2O)_4]_n{^{2n+}}$ polymeric chains, which represents a rare 3D polypseudo-rotaxane MOF from intercalation of 1D and 2D framework. In addition, the luminescent property and electrochemical behavior of compound 1 have been investigated.

키워드

Flexible bis-pyridyl-bis-amide ligand Polypseudo-rotaxane network Hydrothermal synthesis Luminescent property Cyclic voltammetry

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