This study aims to investigate advantages of complex installation of green roof and PV system in a public building, to analyze the impact of green roof on the efficiency of PV power generation, and to consider the correlation between green roof and PV power generation. When the temperature and power generation of the modules installed in the green roof and non-green roof of the public building were measured for 3 days, the average temperature of the green roof was 23.6 degrees, and it was 36.1 degrees in the non-green roof which increased by nearly 53%. Overall, the module temperature in the green roof was lower. On the other hand, in relation to the PV generation depending on temperature reduction during the same period, the mono-crystalline module and the poly-crystalline module in the green roof showed an increase in generation at nearly 222.2W and 341.6W, and the efficiency rose by 5.5% and 6.2%, respectively, compared to the modules in the non-green roof. Therefore, it is analyzed that green roof has a positive influence on PV power generation. Finally shows the efficiency of the installed on the Green Roof PV system (complex Installation) higher than on the concrete roof PV system. Thus, the complex PV systems as well as the usual benefits of green roofs will provide greater synergies.