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Construction of 19F-13C Solid-State NMR Probe for 400MHz Wide-Bore Magnet
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  • Construction of 19F-13C Solid-State NMR Probe for 400MHz Wide-Bore Magnet
  • Construction of 19F-13C Solid-State NMR Probe for 400MHz Wide-Bore Magnet
저자명
Jeong. Ji-Ho,Park. Yu-Geun,Choi. Sung-Sub,Kim. Yongae
간행물명
Journal of the Korean magnetic resonance society
권/호정보
2013년|17권 2호|pp.81-85 (5 pages)
발행정보
한국자기공명학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Various fluorine-containing materials are used in electronic devices like LCD display panels and Li-ion batteries. The structural conformation of fluorine in fluorinated materials is an important contributing factor that influences the chemical and physical properties. The conformation can be changed by heat and stress during manufacture or use. Understanding the conformational changes is critical for understanding the performance and durability of electronic devices. Solid-state NMR spectroscopy could be widely used for the analysis of various fluorine-containing materials for electronic devices. However, conventional CPMAS probes cannot be used for in-situ analysis of fluorine-containing electronic devices like LCD panels and Li-ion batteries. In this paper, we show the design, construction, and optimization of a $^{19}F-^{13}C$ double-resonance solid-state NMR probe for a 400MHz wide-bore magnet with a flat square coil for in-situ analysis of fluorine-containing electronic devices without observing fluorine background signals. This custom-built probe does not show any fluorine background signals, and can have higher efficiency for lossy samples.