Unconventional natural gas resources are now estimated to be as large as conventional resources. Unconventional natural gas has became an increasingly important source of energy in the world since the start of this century. The factors that drive natural gas demand and supply point more and more to a future in which natural gas plays greater role in the global energy mix. The expansion of using natural gas will be expected in Korea. This research aims to analyze environmental impacts of expansion of unconventional natural gas. This research was carried out for comparative analysis between global energy mix and Korea energy mix, and developed a case that reflect the changed energy mix due to the expansion of unconventional natural gas in Korea. Also this research evaluate the production of air pollutants and the cost of the damage in power generation sector. The results of this research can be summarized as that natural gas portion of future global energy mix (about 25%) is greater than Korea energy mix (about 12%). This research developed a case that replace 10% energy of power generation sector to natural gas in the 6th demand supply program, reflecting the changed energy mix due to the expansion of natural gas use. In that case, air pollutants would be reduced gradually through 2015 to 2027. In detail, carbon dioxide reduces 22 million tons and environmental damage cost reduces 4500 billion won by 2027.