In this study, the quick HPLC-MS/MS method for the simultaneous separation of 2-acetyl-4(5)-tetrahydroxybuthylimidazole (THI) and 4-(5)-methylimidazole (4-MI) in alkaline medium was used for caramel color and processed foods in Korea. After a simple sample pretreatment, 51 4-MI-labeled samples were positive for 4-MI and 2 also contained THI. The concentration of 4-MI was 260.5~24, $499.3{mu}g/kg$ in caramel color, less than $LOD{sim}1,712.5{mu}g/kg$ in sauce, 1,242.3, $5,972.2{mu}g/kg$ in balsamic vinegar, $2,118.3{sim}5,802.4{mu}g/kg$ in complex seasoning, $82.7{sim}5,110.6{mu}g/kg$ in curry, and $29.9{sim}464.4{mu}g/kg$ in soft drinks. The recovery rate of 4-MI was 97.1~111.0% in sauce and 81.9~110.0% in powder and that of THI was 83.6{sim}106.4% in sauce and 61.2{sim}99.4% in powder. Our results concluded a safe amount of 4-MI and THI compared to the limit of Korea additive code but the processed foods do not have a limit of caramel color and 4-MI in Korea. Therefore, research and monitoring of 4-MI and THI is needed for processed foods in Korea.