This study was performed to verify the structural reinforcing effect of recycled polyethylene terephthalate (PET) fiber. In order to verify the structural reinforcing capacity of RPET fiber, recycled PET fiber added RC slab specimens were prepared to examine the flexural capacity while those of plain concrete and those of added with PP fiber, and the behavior of the specimens were also evaluated. The result shows that the compressive strength reduces as the fiber volume fraction increases, and the rate of reduction varies from 2% to 7%. The result of the flexural capacity shows that the ultimate capacity of plain specimens is the highest compare to those fiber reinforced specimens, but it has shown that specimens reinforced by 5% PET fiber has the highest energy absorption and the ductility index. In the application of PET fiber in slab specimens has shown that ductility capacity have increased where the ultimate capacity decreasing. That is the different tendency of beam specimens, which the ultimate capacity and the ductility of those have both shown the improvement compare to plain concrete specimens, which means the reinforcing effect of PET fiber in slab is less strong than in beam. Therefore, the application of PET fiber in slab structures as reinforcement needs the proper mix proportion of concrete and volume fraction of PET fiber with deep consideration of the structures.