- 수환경 특성에 따른 은과 이산화티탄 나노입자의 응집 특성 연구
- ㆍ 저자명
- 임명희,배수진,이용주,이성규,황유식,Lim. Myunghee,Bae. Sujin,Lee. Yong-Ju,Lee. Sung-Kyu,Hwang. Yu Sik
- ㆍ 간행물명
- 上下水道學會誌
- ㆍ 권/호정보
- 2013년|27권 5호|pp.571-579 (9 pages)
- ㆍ 발행정보
- 대한상하수도학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The aggregation behaviors of silver nanoparticles (AgNPs) and titanium dioxide ($TiO_2$) nanoparticles were investigated. Time-resolved dynamic light scattering (DLS) was used to study the initial aggregation of AgNPs and $TiO_2$ over a range of mono (NaCl) and divalent ($CaCl_2$) electrolyte concentrations. The effects of pH, initial concentration of NPs and natural organic matters (NOM) on the aggregation of NPs were also investigated. The aggregation of both nanoparticles showed classical Derjaguin-Landau-Verwey-Overbeek (DLVO) type behavior. Divalent electrolyte was more efficient in destabilize the AgNPs and $TiO_2$ than monovalent electrolyte. The effect of pH on the aggregation of AgNPs was not significant. But the aggregation rate of $TiO_2$ was much higher with increasing pH. Higher NPs concentration leads to faster aggregation. Natural organic matter (NOM) was found to substantially hinder the aggregation of both AgNPs and $TiO_2$. This study found that the aggregation behavior of AgNPs and $TiO_2$ are closely associated with environmental factors such as ionic strength, pH, initial concentration of NPs and NOM.