기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Effect of Passivation on the Sintering Behavior of Submicron Nickel Powder Compacts for MLCC Application
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Effect of Passivation on the Sintering Behavior of Submicron Nickel Powder Compacts for MLCC Application
  • Effect of Passivation on the Sintering Behavior of Submicron Nickel Powder Compacts for MLCC Application
저자명
Jo. Gi-Young,Lee. Kwi-Jong,Kang. Suk-Joong L.
간행물명
한국분말야금학회지
권/호정보
2013년|20권 6호|pp.405-410 (6 pages)
발행정보
한국분말야금학회
파일정보
정기간행물|ENG|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

During sintering of Ni-electrode multi-layer ceramic capacitors (MLCCs), the Ni electrode often becomes discontinuous because of its lower sintering temperature relative to that of $BaTiO_3$. In an attempt to retard the sintering of Ni, we introduced passivation of the Ni powder. To find the optimal passivation conditions, a thermogravimetric analysis (TGA) was conducted in air. After passivation at $250^{circ}C$ for 11 h in air, a nickel oxide shell with a thickness of 4-5 nm was formed on nickel nanoparticles of 180 nm size. As anticipated, densification of the compacts of the passivated Ni/NiO core-shell powder was retarded: the starting temperature of densification increased from ${sim}400^{circ}C$ to ${sim}600^{circ}C$ in a $97N_2-3H_2$ (vol %) atmosphere. Grain growth was also retarded during sintering at temperatures of 750 and $1000^{circ}C$. When the sintering atmosphere was changed from wet $99.93N_2-0.07H_2$ to wet $99.98N_2-0.02H_2$, the average grain size decreased at the same sintering temperature. The conductivity of the passivated powder sample sintered at $1150^{circ}C$ for 8 h in wet $99.93N_2-0.07H_2$ was measured to be $3.9{ imes}10^4S/cm$, which is comparable with that, $4.6{ imes}10^4S/cm$, of the Ni powder compact without passivation. These results demonstrate that passivation of Ni is a viable means of retarding sintering of a Ni electrode and hence improving its continuity in the fabrication of $BaTiO_3$-based multi-layer ceramic capacitors.