We examined the generation of harmonic voltage by a synchronous machine adding d-axis and q-axis harmonic field windings in order to reduce the harmonics in a power line. We derived the expressions of the armature voltage in the case of supplying the currents with the frequency nf to the d-axis and q-axis harmonic field windings. We constructed the synchronous machine adding the harmonic windings. In this paper, the expressions and the experimental results on the generation of harmonic voltages by the synchronous machine are presented.