Since electrical resistivity of concrete can be measured in a more rapid and simple way than chloride diffusivity, it should be primarily regular quality control of the electrical resistivity of concrete which provides the basis for indirect of quality control of chloride diffusivity during concrete construction. If this is realized, the electrical resistivity of concrete can be a crucial parameter to establish maintenance strategy for marine concrete structures. The purpose of this study is to develop, design and test a surface electrical resistivity measurement protocol. Microstructural affecting factors such as capillary water, porosity, tourtousity, and so on, on the electrical resistivity of concrete were examined taking into account for mixing proportion properties, and hydration stage. This study can provide a non-destructive approach for durability design of marine concrete. From the relationship between electrical resistivity and chloride diffusivity, it is expected that the result is subsequently used as a calibration curve for an indirect control of the chloride diffusivity based on regular measurements of the electrical resistivity during concrete construction.