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금속담지 활성알루미나 촉매의 암모니아 저온연소반응
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  • 금속담지 활성알루미나 촉매의 암모니아 저온연소반응
  • Catalytic Oxidation of Ammonia over Metal Supported on Alumina at Low Temperature
저자명
임윤희,이주열,박병현,Lim. Yun-Hui,Lee. Ji-Yeol,Park. Byung-Hyun
간행물명
한국유화학회지
권/호정보
2013년|30권 3호|pp.371-379 (9 pages)
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한국유화학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In order to improve the selective oxidation reaction of gaseous ammonia at a low temperature, various types of metal-impregnated activated alumina were prepared, and also physical and chemical properties of the conversion of ammonia were determined. Both types of metal (Cu, Ag) impregnated activated alumina show high conversion rate of ammonia at high temperature (over $300^{circ}C$). However, at lower temperature ($200^{circ}C$), Ag-impregnated catalyst shows the highest conversion rate (93%). In addition, the effects of lattice oxygen of the developed catalyst was studied. Ce-impregnated catalyst showed higher conversion rate than commercial alumina, but also showed lower conversion rate than Ag-impregnated sample. Moreover, 5 vol.% of Ag activation under hydrogen shows the highest conversion rate result. Finally, through high conversion at low temperature, it was considered that the production of NO and $NO_2$, toxic by-products, were effectively inhibited.