WAVE(Wireless Access for Vehicular Environment) is new concepts and Vehicles communications technology using for ITS(Intelligent Transportation Systems) service by IEEE standard 802.11p. Also it increases the efficiency and safety of the traffic on the road. However, the efficiency of Scrambler bit computational algorithms of OFDM modulation in WAVE systems will fall as it is not able to process in parallel in terms of hardware and software. This paper proposes an algorithm to configure 64-bits matrix table in scambler bit computation as well as an algorithm to compute 64-bits matrix table and input data in parallel. The proposed algorithm on this thesis is executed using 64-bits matrix table. In the result, the processing speed for 1 and 1000 times is improved about 40.08% ~ 40.27% and processing rate per sec is performed more than 468.35 compared to bit operation scramble. And processing speed for 1 and 1000 times is improved about 7.53% ~ 7.84% and processing rate per sec is performed more than 91.44 compared to 32-bits operation scramble. Therefore, if the 64 bit-CPU is used for 64-bits executable scramble algorithm, it is improved more than 40% compare to 32-bits scrambler.