이 연구는 3-(1,8나프탈이미도)프로필메타아크릴레이트(NIPM)와 GMA공중합체의 합성과 물성에 관한 과제로서 나프탈이미드 발색단을 가진 공중합체의 조성, 모노머 반응성비, 공명효과(Q)와 극성효과 (e), 형광특성 등을 조사하였다. Azobisisobutyronitronitryl(AIBN) 개시제와 dimethylformamide(DMF) 용매를 $60^{circ}C$에서 공중합하였다. Fineman-Ross(F-R)와 Kelen-$Tddot{ar{u}}dddot{ ilde{o}}s$(K-T)법으로 부터 단량체 반응성비를 구하였으며, $r_1$값이 $r_2$보다 크게 나타났다. NIPM이 공중합체내에서 GMA보다 더 많음을 알 수 있다. 380 nm에서 약한 분자형광띠와 460 nm에서 강한 중합체 엑시머 형광띠가 나타났다.
This work, which was about the synthesis of 3-(1,8-Naphthalimido) propyl methacrylate and GMA copolymers and their physical properties, investigated the compositions of the copolymer, the reactivity ratios of the monomer, resonance effect(Q), polar effect(e) and fluorescence effect of 1,8-naphthalicanhydride. Azobisisobutyronitronitryl(AIBN) as an initiator was employed at $60^{circ}C$ with dimethylformamide(DMF) of solvent for the copolymerization of NIPM. $r_1$ was found to be higher than $r_2$ from the reactivity ratios of the monomer obtained from F-R and K-T methods. NIPM was found to be more copolymerized than GMA. The fluorescence spectrums of these polymers showed a weak monomer fluorescence band at 380 nm and a strong excimer fluorescence band at about 460 nm.
