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서지반출
Effect of LiCoO2 Cathode Density and Thickness on Electrochemical Performance of Lithium-Ion Batteries
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  • Effect of LiCoO2 Cathode Density and Thickness on Electrochemical Performance of Lithium-Ion Batteries
  • Effect of LiCoO2 Cathode Density and Thickness on Electrochemical Performance of Lithium-Ion Batteries
저자명
Choi. Jaecheol,Son. Bongki,Ryou. Myung-Hyun,Kim. Sang Hern,Ko. Jang Myoun,Lee. Yong Min
간행물명
Journal of electrochemical science and technology
권/호정보
2013년|4권 1호|pp.27-33 (7 pages)
발행정보
한국전기화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The consequences of electrode density and thickness for electrochemical performance of lithium-ion cells are investigated using 2032-type coin half cells. While the cathode composition is maintained by 90:5:5 (wt.%) with $LiCoO_2$ active material, Super-P electric conductor and polyvinylidene fluoride polymeric binder, its density and thickness are independently controlled to 20, 35, 50 um and 1.5, 2.0, 2.5, 3.0, 3.5 g $cm^{-3}$, respectively, which are based on commercial lithium-ion battery cathode system. As the cathode thickness is increased in all densities, the rate capability and cycle life of lithium-ion cells become significantly worse. On the other hand, even though the cathode density shows similar behavior, its effect is not as high as the thickness in our experimental range. This trend is also investigated by cross-sectional morphology, porosity and electric conductivity of cathodes with different densities and thicknesses. This work suggests that the electrode density and thickness should be chosen properly and mentioned in detail in any kinds of research works.