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Solar Energy Conversion by the Regular Array of TiO2 Nanotubes Anchored with ZnS/CdSSe/CdS Quantum Dots Formed by Sequential Ionic Bath Deposition
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  • Solar Energy Conversion by the Regular Array of TiO2 Nanotubes Anchored with ZnS/CdSSe/CdS Quantum Dots Formed by Sequential Ionic Bath Deposition
  • Solar Energy Conversion by the Regular Array of TiO2 Nanotubes Anchored with ZnS/CdSSe/CdS Quantum Dots Formed by Sequential Ionic Bath Deposition
저자명
Park. Soojeong,Seo. Yeonju,Kim. Myung Soo,Lee. Seonghoon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2013년|34권 3호|pp.856-862 (7 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The photoanode electrode of $TiO_2$ nanotubes (NTs) anchored with ZnS/CdSSe/CdS quantum dots (QDs) was prepared by anodization of Ti metal and successive ionic layer adsorption and reaction (SILAR) procedure. The tuning of the band gap of CdSSe was done with controlled composition of Cd, S, or Se during the SILAR. A ladder-like energy structure suitable for carrier transfer was attained with the photoanode electrode. The power conversion efficiency (PCE) of our solar cell fabricated with the regular array of $TiO_2$ NTs anchored with CdSSe/CdS or CdSe/CdS QDs [i.e., (CdSSe/CdS/$TiO_2NTs$) or (CdSe/CdS/$TiO_2NTs$)] was PCE = 3.49% and 2.81% under the illumination at 100 mW/$cm^2$, respectively. To protect the photocorrosion of our solar cell from the electrolyte and to suppress carrier recombination, ZnS was introduced onto CdSSe/CdS. The PCE of our solar cell with the structure of a photoanode electrode, (ZnS/CdSSe/CdS/$TiO_2$ NTs/Ti) was 4.67% under illumination at 100 mW/$cm^2$.