- NiFe2O4/m-ZrO2와 CeO2를 이용한 고온 태양열 열화학 싸이클의 수소 생산
- ㆍ 저자명
- 김철숙,조지현,김동연,서태범,Kim. Chul-Sook,Cho. Ji-Hyun,Kim. Dong-Yeon,Seo. Tae-Beom
- ㆍ 간행물명
- 한국태양에너지학회 논문집
- ㆍ 권/호정보
- 2013년|33권 2호|pp.93-100 (8 pages)
- ㆍ 발행정보
- 한국태양에너지학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Two-step thermochemical cycle using ferrite-oxide($Fe_2O_4$) device was investigated. The $H_2O$(g) was converted into $H_2$ in the first experiment which was performed using a dish type solar thermal system. However the experiment was lasted only for 2 cycles because the metal oxide device was sintered and broken down. Another problem was that the reaction was taken place mainly on a side of the metal oxide device. The m-$ZrO_2$, which was widely known as a material preventing sintering, was applied on the metal oxide device. The ferrite loading rate and the thickness of the metal oxide device were increased from 10.67wt% to 20wt% and from 10mm to 15mm, respectively. The chemical reactor having two inlets was designed in order to supply the reactants uniformly to the metal oxide device. The second-experiment was lasted for 5 cycles, which was for 6 hours. The total amount of the $H_2$ production was 861.30ml. And cerium oxide($CeO_2$) device was used for increasing $H_2$ production rate. $CeO_2$ device had low thermal resistance, however, more $H_2$ production rate than $Fe_2O_4$ device.