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The Magnetic and Magnetocaloric Properties of the Perovskite La0.7Ca0.3Mn1-xNixO3
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  • The Magnetic and Magnetocaloric Properties of the Perovskite La0.7Ca0.3Mn1-xNixO3
저자명
Hua. Sihao,Zhang. Pengyue,Yang. Hangfu,Zhang. Suyin,Ge. Hongliang
간행물명
Journal of magnetics
권/호정보
2013년|18권 1호|pp.34-38 (5 pages)
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한국자기학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This paper studies the effects of the Mn-site substitution by nickel on the magnetic properties and the magnetocaloric properties of $La_{0.7}Ca_{0.3}Mn_{1-x}Ni_xO_3$ (x = 0, 0.05 and 0.1). The orthorhombic crystal structures of the samples are confirmed by the room temperature X-ray diffraction. The dependence of the Curie temperature ($T_C$) and the magnetic entropy change (${Delta}S_M$) on the Ni doping content was investigated. The samples with x = 0 had the first order phase transition, while the samples with x = 0.05 and 0.1 had the second order phase transition. As the concentration of Ni increased, the maximum entropy change (${mid}{Delta}S_M{mid}_{max}$) decreased gradually, from 2.78 $J{cdot}kg^{-1}{cdot}K^{-1}$ (x = 0) to 1.02 $J{cdot}kg^{-1}{cdot}K^{-1}$ (x = 0.1), in a magnetic field change of 15 kOe. The measured value of $T_C$ was 185 K, 150 K and 145 K for x = 0, 0.05 and 0.1, respectively. The phase transition temperatures became wider as x increased. It indicates that the Mn-site substitution by Ni may be used to tailor the Curie temperature in $La_{0.7}Ca_{0.3}Mn_{1-x}Ni_xO_3$.