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화학적 침출법을 통한 표면 다공성 Al-Cu-Si 공정 합금 제조
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  • 화학적 침출법을 통한 표면 다공성 Al-Cu-Si 공정 합금 제조
저자명
이준학,김정태,임수현,박혜진,신호정,박규현,김기범,Lee. Joonhak,Kim. Jungtae,Im. Soohyun,Park. Hyejin,Shin. Hojung,Park. Kyuhyun,Kim. Kibeum
간행물명
한국재료학회지
권/호정보
2013년|23권 4호|pp.227-232 (6 pages)
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한국재료학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Al-based alloys have recently attracted considerable interest as structural materials and light weight materials due to their excellent physical and mechanical properties. For the investigation of the potential of Al-based alloys, a surface porous $Al_{88}Cu_6Si_6$ eutectic alloy has been fabricated through a chemical leaching process. The formation and microstructure of the surface porous $Al_{88}Cu_6Si_6$ eutectic alloy have been investigated using X-ray diffraction and scanning electron microscopy. The $Al_{88}Cu_6Si_6$ eutectic alloy is composed of an ${alpha}$-Al dendrite phase and a single eutectic phase of $Al_2Cu$ and ${alpha}$-Al. We intended to remove only the ${alpha}$-Al phase and then the $Al_2Cu$ phase would form a porous structure on the surface with open pores. Both acidic and alkaline aqueous chemical solutions were used with various concentrations to modify the influence on the microstructure and the overall chemical reaction was carried out for 24 hr. A homogeneous open porous structure on the surface was revealed via selective chemical leaching with a $H_2SO_4$ solution. Only the ${alpha}$-Al phase was successfully leached while the morphology of the $Al_2Cu$ phase was maintained. The pore size was in a range of $1{sim}5{mu}m$ and the dealloying depth was nearly $3{mu}m$. However, under an alkaline NaOH, aqueous solution, an inhomogeneous porous structure on the surface was formed with a 5 wt% NaOH solution and the morphology of the $Al_2Cu$ phase was not preserved. In addition, the sample that was leached by using a 7 wt% NaOH solution crumbled. Al extracted from the Al2Cu phase as ${alpha}$-Al phase was dealloyed, and increasing concentration of NaOH strongly influenced the morphology of the $Al_2Cu$ phase and sample statement.