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Electrochemical Determination of Bisphenol A at Carbon Nanotube-Doped Titania-Nafion Composite Modified Electrode
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  • Electrochemical Determination of Bisphenol A at Carbon Nanotube-Doped Titania-Nafion Composite Modified Electrode
  • Electrochemical Determination of Bisphenol A at Carbon Nanotube-Doped Titania-Nafion Composite Modified Electrode
저자명
Kim. Byung Kun,Kim. Ji Yeon,Kim. Dong-Hwan,Choi. Han Nim,Lee. Won-Yong
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2013년|34권 4호|pp.1065-1069 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A highly sensitive electrochemical detection method for bisphenol A (BPA) has been developed by using multi-walled carbon nanotube (CNT)-doped titania-Nafion composite modified glassy carbon (GC) electrode. The CNT-titania-Nafion/GC electrode exhibited excellent electrocatalytic activity towards BPA. Therefore, the CNT-titania-Nafion/GC electrode showed improved voltammetric responses for BPA compared to that obtained with bare GC electrode. In addition, cetyltrimethylammonium bromide (CTAB), a cationic surfactant, was added into the BPA sample solution in order to accumulate BPA through hydrophobic interaction between CTAB and BPA. The CNT-titania-Nafion/GC electrode gave a linear response ($r^2$ = 0.999) for BPA from $1.0{ imes}10^{-8}$ M to $5.0{ imes}10^{-6}$ M with a detection limit of $9.0{ imes}10^{-10}$ M (S/N = 3). The modified electrode showed good selectivity against interfering species and also exhibited good reproducibility. The present electrochemical sensor based on the CNT-titania-Nafion/GC electrode was applied to the determination of BPA in food package samples.