We are interested in the rate of convergence of solutions of 2D Navier-Stokes equations in a smooth bounded domain as the viscosity tends to zero under Navier friction condition. If the initial velocity is smooth enough($u{in}W^{2,p}$, p>2), it is known that the rate of convergence is linearly propotional to the viscosity. Here, we consider the rate of convergence for nonsmooth velocity fields when the gradient of the corresponding solution of the Euler equations belongs to certain Orlicz spaces. As a corollary, if the initial vorticity is bounded and small enough, we obtain a sublinear rate of convergence.