Modern gasoline engines with dual injection system improve combustion efficiency by using the two injection commands simultaneously. Due to the different dynamics in the two injection paths, the transient air-fuel ratio (A/F) performance when the injection authority is changed remarkably affects the emission performance of the engine system. For this kind of engines, this paper proposes a model-based design approach that gives a dynamic feedforward compensation for achieving good transient A/F performance. Actually, this work centers on discussing the mean-value model parameters for characterizing the wall-wetting phenomenon when the port injection authority is changed under different engine operation conditions. Moreover, from the view of practice, taking into account the event-based physics of the engine system, significant calibration for the model parameters that are employed for achieving the feedforward compensation is investigated experimentally. Finally, experimental validation results demonstrate the improvement of the transient A/F performance by using the control scheme.