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Aqueous Degradation of Imidacloprid and Fenothiocarb using Contact Glow Discharge Electrolysis: Degradation Behavior and Kinetics
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  • Aqueous Degradation of Imidacloprid and Fenothiocarb using Contact Glow Discharge Electrolysis: Degradation Behavior and Kinetics
  • Aqueous Degradation of Imidacloprid and Fenothiocarb using Contact Glow Discharge Electrolysis: Degradation Behavior and Kinetics
저자명
Hong. Su-Myeong,Min. Zaw Win,Mok. Chulkyoon,Kwon. Hye-Young,Kim. Taek-Kyum,Kim. Doo-Ho
간행물명
Food science and biotechnology
권/호정보
2013년|22권 6호|pp.1773-1778 (6 pages)
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한국식품과학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Degradation of the pesticides fenothiocarb and imidacloprid in water using contact glow discharge electrolysis (CGDE) achieved rates of 57.8 and 43.2% respectively. Degradation was enhanced using citric or hydrochloric acid to lower the pH to 3.0. Both acids enhanced both the degradation rate and the amount. Fenothiocarb degradation was 77.14% at pH 3 with citric acid, and 100% with HCl. Degradation of imidacloprid at pH 3 was 70.18% with citric acid and 93.02% with HCl. Acidic conditions favor either production of $^{cdot}OH$ radicals or enhancement of the degradation of organic compounds by $^{cdot}OH$. Both the degradation rates and amounts for fenothiocarb and imidacloprid were reduced in the presence of methanol due to competition between pesticides and MeOH for $^{cdot}OH$. Degradation of pesticides was not completely inhibited by MeOH. Degradation of both fenothiocarb and imidacloprid using CGDE obeys a first-order rate law with high regression coefficient values ($R^2$ >0.99).