This paper describes a method for the preparation of porous polymethylmethacrylate showing optical reflectivity from the porous silicon template. A porous polymethylmethacrylate showing optical reflectivity was prepared by replicating porous silicon template which was obtained by applying a computer-generated periodic square current density and resulted in a mirror with high reflectivity in a specific narrow spectral region. A porous polymethylmethacrylate showing an excellent reflectivity was successfully obtained by dissolving the Porous silicon template from the porous polymethylmethacrylate composite film. A porous polymethylmethacrylate exhibited a sharp reflection resonance in the reflectivity spectrum. Surface image of the porous polymethylmethacrylate indicated that the surface of the porous polymethylmethacrylate film had a porous structure. These porous polymethylmethacrylate films in aqueous solutions were stable for several days without any degradation.