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Spectral and Geometrical Study of Two Cadmium Complexes, mer-R,S-[Cd(aepn)2]X2 (X: I-, Cl-, aepn: N-(2-Aminoethyl)-1,3-propanediamine) Supported by Solution Experiments
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  • Spectral and Geometrical Study of Two Cadmium Complexes, mer-R,S-[Cd(aepn)2]X2 (X: I-, Cl-, aepn: N-(2-Aminoethyl)-1,3-propanediamine) Supported by Solution Experiments
  • Spectral and Geometrical Study of Two Cadmium Complexes, mer-R,S-[Cd(aepn)2]X2 (X: I-, Cl-, aepn: N-(2-Aminoethyl)-1,3-propanediamine) Supported by Solution Experiments
저자명
Hakimi. Mohammad,Mardani. Zahra,Moeini. Keyvan
간행물명
대한화학회지
권/호정보
2013년|57권 4호|pp.447-454 (8 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

In this research, two new complexes of N-(2-aminoethyl)-1,3-propanediamine (aepn), $[Cd(aepn)_2]I_2$ (1) and $[Cd(aepn)_2]Cl_2{cdots}H_2O$ (2), were prepared and identified by elemental analysis, FT-IR, Raman spectroscopy and single-crystal X-ray diffraction. Geometry around the cadmium atom in two complexes by coordination of six nitrogen atoms of two aepn is distorted octahedral. If distortion in the mer-$[Cd(aepn)_2]^{2+}$ cation is disregarded, it has a $C_2$ axis and $C_2$ symmetry. The cyclic voltammetry experiments were carried out to study the complexation process. Two structural surveys on coordination modes and complexes of aepn are presented. A study was carried out using CSD data to estimate the averages of bond lengths for different types of the Cd-N bonds. It was found that the intermolecular $N-H{cdots}I$, $C-H{cdots}I$ hydrogen bonds in 1 and $N-H{cdots}Cl$, $N-H{cdots}O$, $C-H{cdots}O$, $O-H{cdots}Cl$ in 2 stabilized the crystal networks.