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Effect of supercritical carbon dioxide as an exfoliation aid on bio-based polyethylene terephthalate glycol-modified/clay nanocomposites
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  • Effect of supercritical carbon dioxide as an exfoliation aid on bio-based polyethylene terephthalate glycol-modified/clay nanocomposites
  • Effect of supercritical carbon dioxide as an exfoliation aid on bio-based polyethylene terephthalate glycol-modified/clay nanocomposites
저자명
Jang. Kwangho,Lee. Jae Wook,Hong. In-Kwon,Lee. Sangmook
간행물명
Korea-Australia rheology journal
권/호정보
2013년|25권 3호|pp.145-152 (8 pages)
발행정보
한국유변학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Bio-based PETG (bio-based glycol modified polyethylene terephthalate, Ecozen T95) / clay (organo-modified montmorillonite, OMMT, C10A) nanocomposites were prepared by co-rotating twin screw extruder attached with supercritical carbon dioxide ($scCO_2$) injection system. The effects of nano-clay and $scCO_2$ on the properties of PETG/clay nanocomposites were investigated by measuring thermal, rheological, tensile, impact, and barrier properties. The thermal and mechanical properties decreased with increasing nano-clay content, but they recovered or even exceeded the properties of neat PETG as $scCO_2$ was added. It was verified due to a good dispersion of the nano-clay in PETG matrix for PETG/clay nanocomposites by XRD, SEM, and TEM. It was thought that $scCO_2$ could be an effective exfoliation agent for many nanocomposites systems as well as for bio-based PET/clay nanocomposites.