The influences of Ca and Fe based oxides as dechlorination sorbents on the product distribution, boiling point distribution of liquid product, concentration of Cl of the products from the pyrolysis of PVC containing combustible wastes were investigated. With Fe based oxides as the sorbents, the yield of liquid product remarkably decreased whereas the decrease of the boiling point distribution of the liquid product was not noticeable. This phenomenon indicated that Fe based oxides worked as catalysts with weak catalytic activity. With Ca based oxides as the sorbents, the yield of liquid product did not decrease and the boiling point distribution of liquid product did not change significantly, but the dechlorination performance of these was much better than that with Fe based oxides.