Unlike the conventional wisdom, observations made during the past decade have revealed that many globular clusters possess more than one stellar population. Here, we have discovered evidence for multiple red giant branches (RGBs) in the globular cluster NGC 6388 from the narrow-band Calcium and Str$ddot{o}$mgren b & y (Caby) photometry. In order to confirm the difference in Calcium abundance, we have acquired the low resolution spectroscopy for these RGB stars. In this paper, we will present results of our photometry and hand in the preliminary results of spectroscopic observations.