- 고온 산소분리막용 고강도 다공성 지지체 제조 및 기계적 특성 연구
- ㆍ 저자명
- 박금숙,성영훈,유지행,우상국,한문희,Park. Geum Sook,Seong. Young-Hoon,Yu. Ji Haeng,Woo. Sang Kuk,Han. Moon Hee
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2013년|50권 6호|pp.423-428 (6 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Porous YSZ ceramics are fabricated using 3 mol% yittria-stabilized zirconia (3YSZ) and NiO with different particlesizes (0.6 and 7 ${mu}m$). Nickel oxide (NiO) is added to the YSZ powder as a pore former with different amounts(40, 50, and 60 vol%) and at different sintering temperatures (1350 and $1400^{circ}C$) are applied in order to evaluate the temperature effects on the pore and mechanical properties. Heat treatment is conducted after sintering at $700^{circ}C$ in $H_2$ for the NiO reduction process; then, Ni is removed using a $HNO_3$ etchant solution. According to the NiO contentand sintering temperatures, 41-67% porous YSZ ceramic is obtained and the flexural strength increases, while the porosity decreases with an increasing sintering temperature. The optimum flexural strength ($136.5{pm}13.4MPa$) and porosity (47%) for oxygen transport porous YSZ membrane can be obtained with 40 vol% of 7 ${mu}m$ NiO particle at a sintering temperature of $1350^{circ}C$.