- 유리탄소의 동시증착에 의한 TRISO 피복입자의 ZrC 코팅층 미세구조와 화학양론비 제어
- ㆍ 저자명
- 고명진,김대종,박지연,조문성,김원주,Ko. Myung-Jin,Kim. Daejong,Park. Ji Yeon,Cho. Moon Sung,Kim. Weon-Ju
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2013년|50권 6호|pp.446-450 (5 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
TRISO coated particles with a ZrC barrier layer were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for a use in a very high temperature gas-cooled reactor (VHTR). The ZrC layer was deposited by the reaction between $ZrCl_4$ and $CH_4$ gases at $1500^{circ}C$ in an $Ar+H_2$ mixture gas. The amount of free carbon codeposited with in ZrC was changed by controlling the dilution gas ratio. Near-stoichiometric ZrC phase was also deposited when an impeller was employed to a $ZrCl_4$ vaporizer which effectively inhibited the agglomeration of $ZrCl_4$ powders during the deposition process. A near-stoichiometric ZrC coating layer had smooth surface while ZrC containing the free carbon had rough surface with tumulose structure. Surface roughness of ZrC increased further as the amount of free carbon increased.