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Growth of Oriented Thick Films of BaFe12O19 by Reactive Diffusion
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  • Growth of Oriented Thick Films of BaFe12O19 by Reactive Diffusion
  • Growth of Oriented Thick Films of BaFe12O19 by Reactive Diffusion
저자명
Fisher. John G.,Vu. Hung,Farooq. Muhammad Umer
간행물명
Journal of magnetics
권/호정보
2014년|19권 4호|pp.333-339 (7 pages)
발행정보
한국자기학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Single crystal growth of $BaFe_{12}O_{19}$ by the solid state crystal growth method was attempted. Seed crystals of ${alpha}-Fe_2O_3$ were pressed into pellets of $BaFe_{12}O_{19}$ + 2 wt% $BaCO_3$ and heat-treated at temperatures between $1150^{circ}C$ and $1250^{circ}C$ for up to 100 hours. Instead of single crystal growth taking place on the seed crystal, BaO diffused into the seed crystal and reacted with it to form a polycrystalline reaction layer of $BaFe_{12}O_{19}$. The microstructure, chemical composition and structure of the reaction layer were studied using scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), x-ray Diffraction (XRD) and micro-Raman scattering and confirmed to be that of $BaFe_{12}O_{19}$. XRD showed that the reaction layer shows a strong degree of orientation in the (h00)/(hk0) planes in the sample sintered at $1200^{circ}C$. $BaFe_{12}O_{19}$ layers with a degree of orientation in the (hk0) planes could also be grown by heat-treating an ${alpha}-Fe_2O_3$ seed crystal buried in $BaCO_3$ powder.