- 전기선폭발법으로 제조된 텅스텐 분말의 산소 조성이 방전플라즈마소결 거동에 미치는 영향
- ㆍ 저자명
- 김철희,이성,김병기,김지순,Kim. Cheol-Hee,Lee. Seong,Kim. Byung-Kee,Kim. Ji Soon
- ㆍ 간행물명
- 한국분말야금학회지
- ㆍ 권/호정보
- 2014년|21권 6호|pp.447-453 (7 pages)
- ㆍ 발행정보
- 한국분말야금학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Effect of oxygen content in the ultrafine tungsten powder fabricated by electrical explosion of wire method on the behvior of spark plasma sintering was investigated. The initial oxygen content of 6.5 wt% of as-fabricated tungsten powder was reduced to 2.3 and 0.7 wt% for the powders which were reduction-treated at $400^{circ}C$ for 2 hour and at $500^{circ}C$ for 1h in hydrogen atmosphere, respectively. The reduction-treated tungsten powders were spark-plasma sintered at $1200-1600^{circ}C$ for 100-3600 sec. with applied pressure of 50 MPa under vacuum of 0.133 Pa. Maximun sindered density of 97% relative density was obtained under the condition of $1600^{circ}C$ for 1h from the tungsten powder with 0.7 wt% oxygen. Sintering activation energy of $95.85kJ/mol^{-1}$ was obtained, which is remarkably smaller than the reported ones of $380{sim}460kJ/mol^{-1}$ for pressureless sintering of micron-scale tungsten powders.