Precision agriculture relies on information technology, whose precondition is providing real-time and accurate information. It depends on various kinds of advanced sensors, such as environmental temperature and humidity, wind speed, light intensity, and other types of sensors. Currently, it is a hot topic how to collect accurate information, the main raw data for agricultural experts, monitored by these sensors timely. Most existing work in WSNs addresses their fundamental challenges, including power supply, limited memory, processing power and communication bandwidth and focuses entirely on their operating system and networking protocol design and implementation. However, it is not easy to find the self-localization capability of wireless sensor networks. Because of constraints on the cost and size of sensors, energy consumption, implementation environment and the deployment of sensors, most sensors do not know their locations. This paper provides maximum likelihood estimators for sensor location estimation when observations are time-of arrival (TOA) range measurement.