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Fabrication of In-needle Microextraction Device Using Nichrome Wire Coated with Poly(ethylene glycol) and Poly(dimethylsiloxane) for Determination of Volatile Compounds in Lavender Oils
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  • Fabrication of In-needle Microextraction Device Using Nichrome Wire Coated with Poly(ethylene glycol) and Poly(dimethylsiloxane) for Determination of Volatile Compounds in Lavender Oils
  • Fabrication of In-needle Microextraction Device Using Nichrome Wire Coated with Poly(ethylene glycol) and Poly(dimethylsiloxane) for Determination of Volatile Compounds in Lavender Oils
저자명
Lee. Eun Ji,Lee. Dong-Sun
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2014년|35권 1호|pp.211-217 (7 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A new needle-based device for headspace wire coated in-needle microextraction (HS-WC-INME) was fabricated using a nichrome wire coated with poly(ethylene glycol) (PEG) and poly(dimethylsiloxane) (PDMS) mixture. The proposed needle device was applied for the determination of volatile compounds in lavender and lavandin essential oils by gas chromatography. Fundamental parameters such as needle design, conditions of extraction and desorption were optimized along with the validation of the extraction and desorption efficiency. The optimal conditions were 30 min extraction at $50^{circ}C$ and 2 min desorption at $240^{circ}C$. The calibration curves showed good linearity with the suitable values of the coefficients of determination ($r^2$) greater than 0.99. The limits of detection for linalyl acetate, ${eta}$-caryophyllene, linalool and (+)-limonene were 7.15, 9.04, 10.79 and 22.26 ng, respectively. Analytical recoveries were acceptable in the test samples, varying from 86.7% to 108.0%. The values of relative standard deviations for run to run showed range less than 0.9% while 3.9% through 7.2% for needle to needle. The proposed PEG-PDMS coating could be more suitable than PDMS coating to extract particular polar groups such as alcohols.