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Branched DNA-based Synthesis of Fluorescent Silver Nanocluster
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  • Branched DNA-based Synthesis of Fluorescent Silver Nanocluster
  • Branched DNA-based Synthesis of Fluorescent Silver Nanocluster
저자명
Park. Juwon,Song. Jaejung,Park. Joonhyuck,Park. Nokyoung,Kim. Sungjee
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2014년|35권 4호|pp.1105-1109 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

While single strand DNAs have been widely used for the scaffold of brightly fluorescent silver nanoclusters (Ag NCs), double strand DNAs have not been as successful. Herein, we report a novel synthetic approach for bright Ag NCs using branched double strand DNAs as the scaffolds for synthesis. X-shaped DNA (X-DNA) and Y-shaped DNA (Y-DNA) effectively stabilized Ag NCs, and both X-DNA and Y-DNA resulted in brightly fluorescent Ag NCs. The concentration and molar ratio of silver and DNA were found important for the fluorescence efficiency. The brightest Ag NC with the photoluminescence quantum efficiency of 19.8% was obtained for the reaction condition of 10 ${mu}M$ X-DNA, 70 ${mu}M$ silver, and the reaction time of 48 h. The fluorescence lifetime was about 2 ns for the Ag NCs and was also slightly dependent on the synthetic condition. Addition of Cu ions at the Ag NC preparations resulted in the quenching of Ag NC fluorescence, which was different to the brightening cases of single strand DNA stabilized Ag NCs.