Recently rise in oil prices feet the burden on not only diesel vehicle driver but also LPG vehicle driver, and get interested in various way to reduce fuel costs. In this study discuss on exhaust emissions characteristics on driving cycle mode and ignition advance condition change of CNG/LPLI Bi-Fuel vehicle. Experimental test was performed by changing the conditions of fuel (LPG/CNG), spark advance (Base, $10^{circ}CA$, $15^{circ}CA$), and driving mode (FTP-75, HWFET, and NEDC). In case of CO emission, in the order of CNG Base, CNG S/A10, S/A15 condition are average reduced -21%, -35%, -29% respectively compared to LPG fuel. The active emission reduction from the initial engine start, spark retard is likely to be beneficial in catalyst warm-up and improve combustion stability rather than spark advance.