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The Enhanced Physico-Chemical and Electrochemical Properties for Surface Modified NiO Cathode for Molten Carbonate Fuel Cells (MCFCs)
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  • The Enhanced Physico-Chemical and Electrochemical Properties for Surface Modified NiO Cathode for Molten Carbonate Fuel Cells (MCFCs)
저자명
Choi. Hee Seon,Kim. Keon,Yi. Cheol-Woo
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2014년|35권 5호|pp.1305-1311 (7 pages)
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The nickel oxide, the most widely used cathode material for the molten carbonate fuel cell (MCFC), has several disadvantages including NiO dissolution, poor mechanical strength, and corrosion phenomena during MCFC operation. The surface modification of NiO with lanthanum maintains the advantages, such as performance and stability, and suppresses the disadvantages of NiO cathode because the modification results in the formation of $LaNiO_3$ phase which has high conductivity, stability, and catalytic activity. As a result, La-modified NiO cathode shows low NiO dissolution, high degree of lithiation, and mechanical strength, and high cell performance and catalytic activity in comparison with the pristine NiO. These enhanced physico-chemical and electrochemical properties and the durability in marine environment allow MCFC to marine application as a auxiliary propulsion system.