POD analysis has been done to investigate the internal flow characteristics using LES calculation results of hybrid rocket combustion chamber. The special emphasis was put on the change in the mode energy distribution caused by the installation of diaphragm compared to the baseline case. Also the comparison was made to investigate the effect of wall blowing on the changes in the mode energy between the regions near and far from the diaphragm. For baseline case, POD results clearly distinguish the primary mode containing most of flow energy from the rest of flow modes (2-9 mode) depicting small scale modes. Also, the increase in the energy of flow modes 2-5 is responsible for the formation of relatively large scale structures due to diaphragm. In addition, the comparison of mode energy distributions of flow fields with diaphragm shows similar patterns in both wall blowing and no blowing case. This implies that the local increase in regression rate just after the diaphragm is directly associated with the increase in energy distributions of 2-5 modes.