Recently, research on Media Access Control (MAC) techniques for underwater acoustic communication has been conducted actively. For successful acoustic communication in underwater conditions, development of environmentally adaptive MAC techniques, which is taking narrow bandwidth, distance, depth, noise level, salinity, multipath and etc into account, is an especially important work. In this paper, knowledge based system is introduced not only to obtain adaptive and optimal communication parameters but also increase network efficiency and availability by requesting change of MAC techniques based on decisions from knowledge-based system Smart Decision Block (SDB). Computer simulations were also conducted to verify the performance of the proposed system in underwater conditions.